The present research aims to investigate the Koranic documentation of Imam Ali’s prayers, as suggested in the third chapter of Sahife-ye-Alaviya. Studies have indicated that regarding a request for guidance from God, it is obvious that the Koran has originally been revealed to guide human beings. Imam Ali’s requests have been compatible with the Koranic verses. For instance, the Imam asks God for a happy and good end of life which is cited in the Koran, where prophet Jacob famously advises his children to remain subservient to God by the time of death. Concerning the request for lawful provision from God, the Imam’s call is also compatible with the Koranic verse. It calls on people to eat lawful provision and refrain from satanic commands, for he is the manifest enemy of man. A large number of books have discussed the positive outcomes of lawful provision from a moral perspective. The Imam asks God to make things convenient for him in yet another discussion, reminding us of the prophet Moses in the Koran. Thus, we learn that this call also conforms to the Koranic verses as God tells the prophet that He made things simple for him. Also, regarding the last request examined in this study, the Imam asks God to save him from predicaments; as we read in the Koran, Prophet Joseph asks God to save him from predicaments. Some verses suggest that the residents of the Heavens consider their triumph to be assistance from God.